Structural and thermoanalytical characterization of self-healing polymer the effect of cross-linking density /
The effect of the gradually formed cross-linked structure on the thermal properties and swelling behaviour of modified poly(vinyl alcohol) was investigated. To this aim, the semi-crystalline polymer was functionalized with aldehyde and amino moieties to produce polymers with dynamic imine cross-link...
Elmentve itt :
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| Dokumentumtípus: | Cikk |
| Megjelent: |
2024
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| Sorozat: | JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
149 No. 7 |
| Tárgyszavak: | |
| doi: | 10.1007/s10973-023-12862-2 |
| mtmt: | 34547597 |
| Online Access: | http://publicatio.bibl.u-szeged.hu/40274 |
| Tartalmi kivonat: | The effect of the gradually formed cross-linked structure on the thermal properties and swelling behaviour of modified poly(vinyl alcohol) was investigated. To this aim, the semi-crystalline polymer was functionalized with aldehyde and amino moieties to produce polymers with dynamic imine cross-links, and, thus, with self-healing or curing ability. With increasing degree of functionalization (0.89–7.12%), denser polymer networks cross-linked by dynamic imine bonds were formed, the samples systematically developed thermoset-like properties compared to the pristine, initially thermoplastic PVA. As a result, the introduction of new moieties into the initial PVA lowered the glass transition (from 65.3 to 35.0 °C) and melting temperatures (from 194 to 161 °C), however, a new peak (T crd ) with growing enthalpy values appeared on the DSC curves, which indicates that more and more energy must be supplied in order to break the imine cross-links formed between the introduced aldehyde and amino groups. The significant impact of the degree of functionalization and cross-linking density on the polymer structure was also clearly demonstrated: the crystallinity decreased as the abundance of the introduced moieties increased and the formation of cross-links proceeded. At the same time, the water desorption enthalpies of the samples increased, suggesting a stronger, chemically cross-linked thermoset-like polymer network compared to the thermoplastic poly(vinyl alcohol). |
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| Terjedelem/Fizikai jellemzők: | 2765-2775 |
| ISSN: | 1388-6150 |