Isolation and Structure Elucidation of Four New Dihydro-ß-agarofuran Polyesters from Euonymus sachalinensis

Isolation and Structure Elucidation of Four New Dihydro-ß-agarofuran Polyesters from Euonymus sachalinensis

Four new dihydro-beta-agarofuran polyesters 1-4 have been isolated from the fruit of Euonymus sachalinensis (Celastraceae) and their structures elucidated by means of H-1 and C-13 NMR spectroscopy, including H-1-H-1 COSY. DEFT, H-1-C-13 COSY and COLOC measurements, mass spectrometry end chemical rea...

Teljes leírás

Elmentve itt :
Bibliográfiai részletek
Szerzők: Hohmann Judit
Nagy Gábor
Günther Gábor
Argay Gyula
Kálmán Alajos
Czira Gábor
Dokumentumtípus: Cikk
Megjelent: 1994
Sorozat:JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 1994 No. 22
Tárgyszavak:
Klinikai orvostan
doi:10.1039/p19940003281

mtmt:2333254
Online Access:http://publicatio.bibl.u-szeged.hu/31962
Leíró adatok
Tartalmi kivonat:Four new dihydro-beta-agarofuran polyesters 1-4 have been isolated from the fruit of Euonymus sachalinensis (Celastraceae) and their structures elucidated by means of H-1 and C-13 NMR spectroscopy, including H-1-H-1 COSY. DEFT, H-1-C-13 COSY and COLOC measurements, mass spectrometry end chemical reactions. The configurations have been determined on the basis of NOESY spectra and X-ray analysis. The isolated compounds are the first native representatives of 3,12-oxygenated dihydro-beta-agarofuran in which the usual macrocycle is missing. The structural similarity of compounds 1-4 and the macrocyclic derivatives is noteworthy from a biogenetic point of view.
Terjedelem/Fizikai jellemzők:3281-3285
ISSN:1472-7781

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