Titania nanotube stabilized BiOCl nanoparticles in visible-light photocatalysis
Photocatalysis is a green approach in environmental organic pollutant decomposition. Lately, considerable improvement in the activity of photocatalysts has been achieved with the realization of p-n heterostructures due to the lifetime extension of the photogenerated charge carriers. Herein, we repor...
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Dokumentumtípus: | Cikk |
Megjelent: |
2017
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Sorozat: | RSC ADVANCES
7 No. 27 |
doi: | 10.1039/c6ra28490f |
mtmt: | 3211576 |
Online Access: | http://publicatio.bibl.u-szeged.hu/11474 |
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520 | 3 | |a Photocatalysis is a green approach in environmental organic pollutant decomposition. Lately, considerable improvement in the activity of photocatalysts has been achieved with the realization of p-n heterostructures due to the lifetime extension of the photogenerated charge carriers. Herein, we report a facile synthesis approach for decorating n-type titanate nanotubes with p-type V-VI-VII compound semiconductor BiOCl nanoparticles. It is well-known that BiOX (X = Cl, Br, I) materials form nanometer-thick platelets, which can eventually assemble into micrometer size flower-like 3D structures. Here, we demonstrate that the tubular titanate support can stabilize BiOCl on its surface in the form of nanoparticles measuring a few nanometers in diameter, instead of forming the well-known bismuth-oxyhalide nanoflowers. Subsequent calcination at 400 °C transforms the pristine titanate structures into one-dimensional anatase nanotubes, along with the formation of a heterojunction at the interface of the emerging Bi2Ti2O7 and anatase phases. The resulting nanocomposite shows activity in visible-light photocatalytic test reactions. © The Royal Society of Chemistry. | |
700 | 0 | 1 | |a Haspel Henrik |e aut |
700 | 0 | 1 | |a Oszkó Albert Zoltán |e aut |
700 | 0 | 1 | |a Kukovecz Ákos |e aut |
700 | 0 | 1 | |a Kónya Zoltán |e aut |
856 | 4 | 0 | |u http://publicatio.bibl.u-szeged.hu/11474/1/RSCAdvances7201716410_u.pdf |z Dokumentum-elérés |