"Smart" molecular engineering of metallomesogens based on Pt(II) terpyridine coordination complexes
A series of ionic tetracoordinated Pt(II) complexes based on terpyridine ligand were synthesized and characterized. Their chemical structures were engineered by using counterions of different coordination strengths and dimensions, namely non-coordinating BF4, weakly coordinating bulky gallate units,...
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| Testületi szerző: | |
| Dokumentumtípus: | Könyv része |
| Megjelent: |
2020
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| Sorozat: | Proceedings of the International Symposium on Analytical and Environmental Problems
26 |
| Kulcsszavak: | Környezetkémia |
| Tárgyszavak: | |
| Online Access: | http://acta.bibl.u-szeged.hu/73947 |
| Tartalmi kivonat: | A series of ionic tetracoordinated Pt(II) complexes based on terpyridine ligand were synthesized and characterized. Their chemical structures were engineered by using counterions of different coordination strengths and dimensions, namely non-coordinating BF4, weakly coordinating bulky gallate units, and small and strongly coordinating chlorine (Cl). The complexes containing lipophilic gallate units exhibit low temperature liquid crystalline properties. The mesomorphic properties were investigated by polarized optical microscopy (POM), differential scanning calorimetry (DSC) and X-ray diffraction studies (SWAXS). Photophysical properties were determined in solution and condensed states. |
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| Terjedelem/Fizikai jellemzők: | 40-42 |
| ISBN: | 978-963-306-771-0 |