Új Fe(II)-komplexek előállítása α-dioximokkal, bórsavval sé észtereivel, szemi- és tioszemikarbazonokkal, schiffbázisokkal, valamint fizikai-kémiai és biológiai vizsgálatuk

In our research project new iron(II) complexes were synthesized with azomethines, such as [Fe(1,4-dibromo-2,3-butane-GlyoxH)2(3-HO-aniline)2], [Fe(1,4-dibromo-2,3-butaneGlyoxH)2(2-amino-pyrimidine)2], [Fe(4-benzyl-2-HO-propiophenone-GlyoxH)2], [Fe(5- methyl-2-hexanone)2(en)], [Fe(5-methyl-2-hexanone...

Teljes leírás

Elmentve itt :
Bibliográfiai részletek
Szerzők: Várhelyi Csaba
Kuzmann Ernő
Pokol György
Szalay Roland
Goga Firuţa
Papp Judit
Golban Ligia Mirabela
Várhelyi Melinda
Kovács Ildikó
Testületi szerző: International Symposium on Analytical and Environmental Problems (23.) (2017) (Szeged)
Dokumentumtípus: Könyv része
Megjelent: 2017
Sorozat:Proceedings of the International Symposium on Analytical and Environmental Problems 23
Kulcsszavak:Kémia, Analitikai kémia, Fizikai kémia
Online Access:http://acta.bibl.u-szeged.hu/56149
Leíró adatok
Tartalmi kivonat:In our research project new iron(II) complexes were synthesized with azomethines, such as [Fe(1,4-dibromo-2,3-butane-GlyoxH)2(3-HO-aniline)2], [Fe(1,4-dibromo-2,3-butaneGlyoxH)2(2-amino-pyrimidine)2], [Fe(4-benzyl-2-HO-propiophenone-GlyoxH)2], [Fe(5- methyl-2-hexanone)2(en)], [Fe(5-methyl-2-hexanone)2(1,2-pn)], [Fe(5-methyl-2-hexanone)2 (1,3-pn)], [Fe(5-methyl-2-hexanone)2(o-fen)], [Fe(2,4,5-trimethoxy-acetophenone-SC)2], [Fe(2,4,5-trimethoxy-acetophenone-TSC)2], [Fe(5-methyl-2-hexanone-SC)2], [Fe(5-methyl-2- hexanone-TSC)2], [Fe(Me-Pr-Glyox)3(BOH)2], [Fe(Me-Pr-Glyox)3(BOMe)2], [Fe(Me-i-BuGlyox)3(BOH)2], [Fe(Me-i-Bu-Glyox)3(BOMe)2], [Fe(Me-i-Bu-Glyox)3(BO-n-propyl)2] (en = ethylenedianine, pn = propylenediamine, fen = phenylenediamine, SC = semicarbazone, TSC = thiosemicarbazone), by reacting iron(II)-chloride with different glyoximes, Schiff-bases, semi- or thiosemicarbazones in suitable solvent. The Schiff-bases were obtained with the condensation of 5-methyl-2-hexanone, with diamines. The semi- or thiosemicarbazones were prepared by the condensation of 2,4,5-trimethoxy-acetophenone or 5-methyl-2-hexanone with semicarbazide or thiosemicarbazide. We analyzed their physicochemical properties using mass spectrometry, infrared-, NMR-, UV–VIS-, Mössbauer-spectroscopy, powder-XRD and thermal analysis (TG, DTG and DTA). The biological activity of complexes, especially their antibacterial activity was also explored. The importance of this class of compounds is gained in biochemistry, since some of them act as antibacterial agents and potential anticancer drugs. Furthermore, some members can play role as catalysts in organic chemistry transformations [1–2].
Terjedelem/Fizikai jellemzők:25-30
ISBN:978-963-306-563-1