Efficient synthesis of hydroxy-substituted cispentacin derivatives
Starting from N-protected cis-and trans-2-aminocyclopent-3-enecarboxylic acid derivatives, isomers of 2-amino-3-hydroxycyclopentanecarboxylic acid (8 and 12) were prepared via oxazoline intermediates, whereas the stereoisomeric 2-amino-3,4-dihydroxycyclopentanecarboxylic acids 14 and 17 were synthes...
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Dokumentumtípus: | Cikk |
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Wiley
2008
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Sorozat: | EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
2008 No. 21 |
doi: | 10.1002/ejoc.200800345 |
mtmt: | 1128281 |
Online Access: | http://publicatio.bibl.u-szeged.hu/10394 |
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041 | |a zxx | ||
100 | 1 | |a Benedek György | |
245 | 1 | 0 | |a Efficient synthesis of hydroxy-substituted cispentacin derivatives |h [elektronikus dokumentum] / |c Benedek György |
260 | |a Wiley |c 2008 | ||
300 | |a 3724-3730 | ||
490 | 0 | |a EUROPEAN JOURNAL OF ORGANIC CHEMISTRY |v 2008 No. 21 | |
520 | 3 | |a Starting from N-protected cis-and trans-2-aminocyclopent-3-enecarboxylic acid derivatives, isomers of 2-amino-3-hydroxycyclopentanecarboxylic acid (8 and 12) were prepared via oxazoline intermediates, whereas the stereoisomeric 2-amino-3,4-dihydroxycyclopentanecarboxylic acids 14 and 17 were synthesized by OsO4-catalyzed oxidation. The enantiomers of 8 and 14 were also prepared by the same pathway. The structures, stereochemistry and relative configurations of the synthesized compounds were proved by NMR spectroscopy. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008). | |
700 | 0 | 1 | |a Palkó Márta |e aut |
700 | 0 | 1 | |a Wéber Edit |e aut |
700 | 0 | 1 | |a Martinek Tamás A. |e aut |
700 | 0 | 1 | |a Forró Enikő |e aut |
700 | 0 | 1 | |a Fülöp Ferenc |e aut |
856 | 4 | 0 | |u http://publicatio.bibl.u-szeged.hu/10394/1/Benedek_et_al_2008_European_Journal_of_Organic_Chemistry_u.pdf |z Dokumentum-elérés |