Új pd-komplexek azometin-származékokkal, és fizikai-kémiai vizsgálatuk
In our research we synthesized novel [Pd(monophenyl-dioxime)2L2] (L = 2-aminopyrimidine, 3-hydroxi-aniline, lepidine) type complexes and with different Schiff-bases: [Pd(acetonyl-acetone)2(diamine)], [Pd(dibenzoyl-methane)2(diamine)] (diamine = ophenylene-diamine, ethylene-diamine, 1,2-, 1,3-propyle...
Elmentve itt :
| Szerzők: | |
|---|---|
| Testületi szerző: | |
| Dokumentumtípus: | Könyv része |
| Megjelent: |
2015
|
| Sorozat: | Proceedings of the International Symposium on Analytical and Environmental Problems
21 |
| Kulcsszavak: | Kémia |
| Online Access: | http://acta.bibl.u-szeged.hu/55915 |
| Tartalmi kivonat: | In our research we synthesized novel [Pd(monophenyl-dioxime)2L2] (L = 2-aminopyrimidine, 3-hydroxi-aniline, lepidine) type complexes and with different Schiff-bases: [Pd(acetonyl-acetone)2(diamine)], [Pd(dibenzoyl-methane)2(diamine)] (diamine = ophenylene-diamine, ethylene-diamine, 1,2-, 1,3-propylene-diamine) by reacting PdCl2, monophenyl-dioxime, respectively Schiff-bases with amine, respectively diamine in the corresponding solvent. We analyzed their physicochemical properties using mass spectrometry, infrared-, NMR-spectroscopy and thermal analysis (TG, DTG and DTA). The Pd-complexes have an important role in many organic chemistry reactions as catalysts [1]. Some of them are used in industry. The Pd precious metal price is high, but compared with Rh, Pt, Ir, or Os is infinitesimal. Regarding the biological activity, they inhibit some enzymes which are important in anti-diabetic therapy. Some of the Pd(II) complexes are anti-glaucoma drug candidates [2]. Due to the similarity between Pd and Pt, the complexes of palladium(II) can be considered as potential anticancer agents [3]. |
|---|---|
| Terjedelem/Fizikai jellemzők: | 8-11 |
| ISBN: | 978-963-306-411-5 |